Adsorption of CO2 on MIL-53(Al): FTIR evidence of the formation of dimeric CO2 species.
نویسندگان
چکیده
FTIR spectra of (12)CO2 and (12)CO2 + (13)CO2 mixtures adsorbed on MIL-53(Al) reveal the formation of highly symmetric dimeric (CO2)2 species connected to two structural OH groups.
منابع مشابه
CO2-Selective Nanoporous Metal-Organic Framework Microcantilevers
Nanoporous anodic aluminum oxide (AAO) microcantilevers are fabricated and MIL-53 (Al) metal-organic framework (MOF) layers are directly synthesized on each cantilever surface by using the aluminum oxide as the metal ion source. Exposure of the MIL53-AAO cantilevers to various concentrations of CO2, N2, CO, and Ar induces changes in their deflections and resonance frequencies. The results of th...
متن کاملDynamics and Separation-based Adsorption of Binary Mixtures of CH4, CO2 and H2S on MIL-47: GCMC and MD Studies
This study aimed to investigate the adsorption of CH4, CO2, H2S at a temperature of 298.15 K and pressurerange of 0.1 to 30 atm, and compare the results with experimental data for MIL-47 using GCMC. Themaximum CH4, CO2 and H2S adsorptions were 3.6, 10.45, and 12.57 mol.kg-1, respectively. In addition, theselectivity for binary mixtures of CH4/CO2 and CH4/H2S was calculated. Th...
متن کاملMWCNT@MIL-53 (Cr) Nanoporous Composite: Synthesis, Characterization, and Methane Storage Property
In this paper, porous metal−organic frameworks (MIL-53 [CrIII (OH).{O2C-C6H4-CO2}.{HO2C-C6H4-CO2H}x]) were hydrothermally synthesized and, then, a hybrid composite of these synthesized porous metal−organic frameworks (MOF) with acid-treated multi-walled carbon nanotubes (MWCNTs) was prepared. The materials were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), Brunau...
متن کاملجداسازی CO2/CH4 با استفاده از غشای ماتریس ترکیبی پلی متیل پنتین ذرات MIL-53
در این مطالعه اثر افزودن ذرات Materials Institute Lavoisier-53, MIL 53 بر خواص گاز تراوایی غشای پلی متیل پنتین (PMP) ارزیابی شد.MIL-53با ترکیب درصدهای 10، 20 و %30 وزنی به ماتریس پلیمری اضافه شد. خواص MIL-53 و غشاهای ساخته شده به روش های مختلفی نظیر آزمون FTIR،SEM و TGA بررسی شد. همچنین آزمون جذب گازهای CO2 و CH4 برای بررسی هر چه دقیق تر خواص گاز تراوایی غشاهای حاصل انجام و داده های جذب با ...
متن کاملPredicting mixture coadsorption in soft porous crystals: experimental and theoretical Study of CO2/CH4 in MIL-53(Al).
We present a synergistic experimental and theoretical study of CO(2)/CH(4) mixture coadsorption in breathing metal-organic framework MIL-53(Al). Mixture adsorption experiments were performed and their results were analyzed by comparing them to predictions made from pure-component adsorption data using the Osmotic Framework Adsorption Solution Theory (OFAST). This analytical model, fully validat...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Chemical communications
دوره 52 7 شماره
صفحات -
تاریخ انتشار 2016